What levels are your alk at over the 24 hour period? The pH numbers you show seem fine, towards the lower end, so either should work for you with the night dosing being a little more stable. I used reactors mostly, but when I did does alk separately I always did it at night since that's when it was consumed the most as corals and coralline algae lay down most of their structure at night. I liked to have a large refuge of algae on a reverse daylight schedule to help keep a constant pH.