Update: I dosed the usual 12mL last night after the lights went out and didn't observe any abnormal pH readings this morning. So I'm not sure the H2O2 caused the drop...
Rob, you're right. I am dosing to clear the water column and combat some dense patches of GHA. Yes I understand H2O2 is a band-aid and does not solve the root cause of the algae, which I attribute to a period of excessive overfeeding while I was away on a trip. I have since corrected that. Conventional wisdom demands a slow-and-steady approach during the first year to allow the tank to "find" itself. Having said that, H2O2 (and the extra O2 it adds to the water) doesn't seem to affect anything in the system other than nuisance algae so I decided to experiment.
Thanks all for the input.